§ Glossary · analytical

Mass spectrometry

Identifies a compound by measuring its mass-to-charge ratio.

Mass spectrometry (MS) ionises a sample and measures the mass-to-charge ratio (m/z) of the resulting ions. For peptides, MS confirms identity by showing that the measured molecular mass matches the theoretical mass calculated from the peptide's amino acid sequence. ESI-MS (electrospray ionisation) and MALDI-TOF are the most common methods for peptide analysis. MS complements HPLC: HPLC tells you how pure the sample is; MS tells you whether the main peak is the right molecule. A research-grade peptide COA usually includes both.

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